a)

$AgNO_3 + HCl \to AgCl + HNO_3$
Theo PTHH : 

$n_{AgCl} = n_{HCl} = n_{AgNO_3} = \dfrac{340.10\%}{170} =0,2(mol)$

$m_{dd\ HCl} = \dfrac{0,2.36,5}{7,3\%} = 100(gam)$

b)

$m_{AgCl} = 0,2.143,5 = 28,7(gam)$

c)

$m_{dd\ sau\ pư} = 340 + 100 -28,7 = 411,3(gam)$

$n_{HNO_3} = n_{AgNO_3} = 0,2(mol)$
$\Rightarrow C\%_{HNO_3} = \dfrac{0,2.63}{411,3}.100\% = 3,06\%$

Đầu tiên bạn tính n H2 = cách bảo toàn e =» n hcl pư =» m dd hcl pư 

Bạn bảo toàn ntố Fe để tím n FeCl2 =» m FeCl2 (dd B)

C% dd B = m FeCl 2 / (m Fe + m dd HCl)

PTHH: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)

Ta có: \(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,1\left(mol\right)\\n_{CuCl_2}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{0,1\cdot36,5}{7,3\%}=50\left(g\right)\\C\%_{CuCl_2}=\dfrac{0,05\cdot135}{4+50}\cdot100\%=12,5\%\end{matrix}\right.\)

\(m_{NaOH}=\dfrac{200\cdot8}{100}=16\left(g\right)\Rightarrow n_{NaOH}=\dfrac{16}{40}=0,4mol\)

\(NaOH+HCl\rightarrow NaCl+H_2O\)

 0,4           0,4         0,4        0,4

a)\(m_{HCl}=0,4\cdot36,5=14,6\left(g\right)\) 

 \(\Rightarrow m_{ddHCl}=\dfrac{14,6}{7,3}\cdot100=200\left(g\right)\)

b)\(m_{NaCl}=0,4\cdot58,5=23,4\left(g\right)\)

   \(m_{H_2O}=0,4\cdot18=7,2\left(g\right)\)

   \(m_{ddsau}=200+200-7,2=392,8\left(g\right)\)

   \(\Rightarrow C\%=\dfrac{23,4}{392,8}\cdot100=5,96\%\)

c) \(n_{SO_2}=\dfrac{6,72}{22,4}=0,3mol\)

     \(2NaOH+SO_2\rightarrow Na_2SO_4+H_2O\)

         0,4          0,3         0,3              0,3

     \(m_{Na_2SO_4}=0,3\cdot142=42,6\left(g\right)\)

- Tính n H2 = cách bảo toàn e =» n hcl pư =» m dd hcl pư

- Bảo toàn nguyên tố Fe để tím n FeCl2 =» m FeCl2 (dd B)

C% dd B = m FeCl 2 / (m Fe + m dd HCl)

Câu 1:

a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

b, \(n_{Zn}=\dfrac{16,25}{65}=0,25\left(mol\right)\)

\(n_{H_2}=n_{Zn}=0,25\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,25.24,79=6,1975\left(l\right)\)

c, \(n_{HCl}=2n_{Zn}=0,5\left(mol\right)\)

\(\Rightarrow m_{HCl}=0,5.36,5=18,25\left(g\right)\)

\(\Rightarrow m_{ddHCl}=\dfrac{18,25}{10\%}=182,5\left(g\right)\)

d, \(n_{ZnCl_2}=n_{Zn}=0,25\left(mol\right)\)

\(\Rightarrow C\%_{ZnCl_2}=\dfrac{0,25.136}{16,25+182,5-0,25.2}.100\%\approx17,15\%\)

Câu 2:

a, \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)

c, \(n_{NaOH}=\dfrac{40}{40}=1\left(mol\right)\)

Theo PT: \(n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,5\left(mol\right)\)

\(\Rightarrow V_{H_2SO_4}=\dfrac{0,5}{2}=0,25\left(l\right)\)

d, \(n_{Na_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,5\left(mol\right)\)

\(\Rightarrow C_{M_{Na_2SO_4}}=\dfrac{0,5}{0,25}=2\left(M\right)\)

\(a.Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O\\ n_{NaCl}=n_{HCl}=2.n_{CO_2}=2.\dfrac{448:1000}{22,4}=0,04\left(mol\right)\\ C_{MddHCl}=\dfrac{0,04}{0,02}=2\left(M\right)\\ b.m_{NaCl}=58,5.0,04=2,34\left(g\right)\\ c.m_{Na_2CO_3}=106.0,02=2,12\left(g\right)\\ \%m_{Na_2CO_3}=\dfrac{2,12}{5}.100=42,4\%\\ \%m_{NaCl}=100\%-42,4\%=57,6\%\)

Bài 16 : 

\(n_{CO2}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\)

Pt : \(Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O|\)

            1              2                2           1         1

           0,02         0,04           0,04     0,02

a) \(n_{HCl}=\dfrac{0,02.2}{1}=0,04\left(mol\right)\)

 20ml = 0,02l

\(C_{M_{HCl}}=\dfrac{0,04}{0,02}=2\left(M\right)\)

b) \(n_{NaCl}=\dfrac{0,02.2}{1}=0,04\left(mol\right)\)

⇒ \(m_{NaCl}=0,04.58,5=2,34\left(g\right)\)

c) \(n_{Na2CO3}=\dfrac{0,04.1}{2}=0,02\left(mol\right)\)

 ⇒ \(m_{Na2CO3}=0,02.106=2,12\left(g\right)\)

\(m_{NaCl}=5-2,12=2,88\left(g\right)\)

⁰/₀Na₂CO₃ = \(\dfrac{2,12.100}{5}=42,4\)⁰/₀

⁰/₀NaCl = \(\dfrac{2,88.100}{5}=57,6\)⁰/₀

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